Homogeneous Organic Reductant Based on 4,4'-tBu2-2,2'-Bipyridine for Cross-Electrophile Coupling.
Charboneau DJ, Huang H, Barth EL, Deziel AP, Germe CC, Hazari N, Jia X, Kim S, Nahiyan S, Birriel-Rodriguez L, Uehling MR.
Charboneau DJ, et al.
Tetrahedron Lett. 2024 Jul 28;145:155159. doi: 10.1016/j.tetlet.2024.155159. Epub 2024 Jun 19.
Tetrahedron Lett. 2024.
PMID: 39036418
(t)Bu-OED(4) has a reduction potential of -1.33 V (vs Ferrocenium/Ferrocene) and is soluble in a range of common organic solvents. We demonstrate that (t)Bu-OED(4) can facilitate Ni/Co dual-catalyzed C(sp(2))-C(sp(3)) cross-electrophile coupling reactions and is highly fun …
(t)Bu-OED(4) has a reduction potential of -1.33 V (vs Ferrocenium/Ferrocene) and is soluble in a range of common organic solvents. We …