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Rational Design and Reticulation of Infinite qbe Rod Secondary Building Units into Metal-Organic Frameworks through a Global Desymmetrization Approach for Inverse C3 H8 /C3 H6 Separation.
Gong W, Xie Y, Yamano A, Ito S, Reinheimer EW, Dong J, Malliakas CD, Proserpio DM, Cui Y, Farha OK. Gong W, et al. Angew Chem Int Ed Engl. 2024 Jan 25;63(5):e202318475. doi: 10.1002/anie.202318475. Epub 2023 Dec 22. Angew Chem Int Ed Engl. 2024. PMID: 38078602 Free article.
Reticulating Crystalline Porous Materials for Asymmetric Heterogeneous Catalysis.
Han X, Li W, Yang B, Jiang C, Qu Z, Xu H, Liu Y, Cui Y. Han X, et al. Adv Mater. 2024 Dec 30:e2415574. doi: 10.1002/adma.202415574. Online ahead of print. Adv Mater. 2024. PMID: 39740186 Review.
This review overviews recent developments in chiral MOFs (CMOFs) and chiral COFs (CCOFs), focusing on their design strategies, and synthetic methods, and highlights the structure-property relationships that connect key structural features to asymmetric catalytic performanc …
This review overviews recent developments in chiral MOFs (CMOFs) and chiral COFs (CCOFs), focusing on their design strategies, and synthetic …
Homochiral Covalent Organic Frameworks with Superhelical Nanostructures Enable Efficient Chirality-Induced Spin Selectivity.
Hou B, Wang K, Jiang C, Guo Y, Zhang X, Liu Y, Cui Y. Hou B, et al. Angew Chem Int Ed Engl. 2024 Dec 16;63(51):e202412380. doi: 10.1002/anie.202412380. Epub 2024 Oct 22. Angew Chem Int Ed Engl. 2024. PMID: 39180764
This approach yields homochiral 3D COFs 13-OR with a 10-fold interpenetrated diamondoid structure (R=H, Me, Et, (n)Pr, (n)Bu) from enantiopure 1,1'-bi-2-naphthol (BINOL)-based tetraaldehydes and tetraamine. ...
This approach yields homochiral 3D COFs 13-OR with a 10-fold interpenetrated diamondoid structure (R=H, Me, Et, (n)Pr, (n)Bu) from en …