Changes in the electronic structure around Ni in oxidized and reduced selenium-containing hydrogenases from Methanococcus voltae.
Sorgenfrei O, Duin EC, Klein A, Albracht SP.
Sorgenfrei O, et al. Among authors: klein a.
Eur J Biochem. 1997 Jul 15;247(2):681-7. doi: 10.1111/j.1432-1033.1997.00681.x.
Eur J Biochem. 1997.
PMID: 9266713
Free article.
A 90 degree flip of the electronic z-axis is proposed to explain the hyperfine interaction in both states. This has been demonstrated previously only for the F420-non-reducing hydrogenase from M. voltae, where the selenium atom is present as a selenocysteine residue …
A 90 degree flip of the electronic z-axis is proposed to explain the hyperfine interaction in both states. This has been demonstrated …