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Genuine quadruple bonds between two main-group atoms. Chemical bonding in AeF- (Ae = Be-Ba) and isoelectronic EF (E = B-Tl) and the particular role of d orbitals in covalent interactions of heavier alkaline-earth atoms.
Liu R, Qin L, Zhang Z, Zhao L, Sagan F, Mitoraj M, Frenking G. Liu R, et al. Among authors: zhao l. Chem Sci. 2023 Apr 4;14(18):4872-4887. doi: 10.1039/d3sc00830d. eCollection 2023 May 10. Chem Sci. 2023. PMID: 37181783 Free PMC article.
Silylene-Stabilized Neutral Dibora-Aromatics with a B═B Bond.
Fan J, Xu J, Ma Q, Yao S, Zhao L, Frenking G, Driess M. Fan J, et al. Among authors: zhao l. J Am Chem Soc. 2024 Jul 24;146(29):20458-20467. doi: 10.1021/jacs.4c06579. Epub 2024 Jul 9. J Am Chem Soc. 2024. PMID: 38980827 Free PMC article.
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