Swart M - Search Results

1

10-Fold Increase in Hydrogen Atom Transfer Reactivity for a Series of S = 1 Fe^IV═O Complexes Over the S = 2 [(TQA)Fe^IV═O]²⁺ Complex via Entropic Lowering of Reaction Barriers by Secondary Sphere Cycloalkyl Substitution.

Das A, Pal N, Xiong J, Young VG Jr, Guo Y, Swart M, Que L Jr. Das A, et al. Among authors: swart m. J Am Chem Soc. 2024 Dec 19. doi: 10.1021/jacs.4c10120. Online ahead of print. J Am Chem Soc. 2024. PMID: 39699233

2

Sc³⁺-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O₂ to Generate a Complex with an Fe^IV₂(μ-O)₂ Core.

Banerjee S, Draksharapu A, Crossland PM, Fan R, Guo Y, Swart M, Que L Jr. Banerjee S, et al. Among authors: swart m. J Am Chem Soc. 2020 Mar 4;142(9):4285-4297. doi: 10.1021/jacs.9b12081. Epub 2020 Feb 19. J Am Chem Soc. 2020. PMID: 32017545 Free PMC article.

3

Reactivity of an Fe^IV-Oxo Complex with Protons and Oxidants.

Hill EA, Weitz AC, Onderko E, Romero-Rivera A, Guo Y, Swart M, Bominaar EL, Green MT, Hendrich MP, Lacy DC, Borovik AS. Hill EA, et al. Among authors: swart m. J Am Chem Soc. 2016 Oct 12;138(40):13143-13146. doi: 10.1021/jacs.6b07633. Epub 2016 Sep 30. J Am Chem Soc. 2016. PMID: 27647293 Free PMC article.

4

A tale of two topological isomers: Uptuning [Fe^IV(O)(Me₄cyclam)]²⁺ for olefin epoxidation.

Chandra B, Ahsan F, Sheng Y, Swart M, Que L Jr. Chandra B, et al. Among authors: swart m. Proc Natl Acad Sci U S A. 2024 Mar 19;121(12):e2319799121. doi: 10.1073/pnas.2319799121. Epub 2024 Mar 13. Proc Natl Acad Sci U S A. 2024. PMID: 38478690 Free PMC article.

5

Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex.

Padamati SK, Angelone D, Draksharapu A, Primi G, Martin DJ, Tromp M, Swart M, Browne WR. Padamati SK, et al. Among authors: swart m. J Am Chem Soc. 2017 Jun 28;139(25):8718-8724. doi: 10.1021/jacs.7b04158. Epub 2017 Jun 20. J Am Chem Soc. 2017. PMID: 28581745 Free PMC article.

6

Stoichiometric Formation of an Oxoiron(IV) Complex by a Soluble Methane Monooxygenase Type Activation of O₂ at an Iron(II)-Cyclam Center.

Kass D, Corona T, Warm K, Braun-Cula B, Kuhlmann U, Bill E, Mebs S, Swart M, Dau H, Haumann M, Hildebrandt P, Ray K. Kass D, et al. Among authors: swart m. J Am Chem Soc. 2020 Apr 1;142(13):5924-5928. doi: 10.1021/jacs.9b13756. Epub 2020 Mar 18. J Am Chem Soc. 2020. PMID: 32168447

7

Tuning the Reactivity of Terminal Nickel(III)-Oxygen Adducts for C-H Bond Activation.

Pirovano P, Farquhar ER, Swart M, McDonald AR. Pirovano P, et al. Among authors: swart m. J Am Chem Soc. 2016 Nov 2;138(43):14362-14370. doi: 10.1021/jacs.6b08406. Epub 2016 Oct 24. J Am Chem Soc. 2016. PMID: 27739688 Free PMC article.

8

A 4H⁺/4e^- Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex.

Wu T, Rajabimoghadam K, Puri A, Hebert DD, Qiu YL, Eichelberger S, Siegler MA, Swart M, Hendrich MP, Garcia-Bosch I. Wu T, et al. Among authors: swart m. J Am Chem Soc. 2022 Sep 21;144(37):16905-16915. doi: 10.1021/jacs.2c05454. Epub 2022 Sep 9. J Am Chem Soc. 2022. PMID: 36083845 Free PMC article.

9

Reductive Coupling of Nitric Oxide by Cu(I): Stepwise Formation of Mono- and Dinitrosyl Species En Route to a Cupric Hyponitrite Intermediate.

Bhadra M, Albert T, Franke A, Josef V, Ivanović-Burmazović I, Swart M, Moënne-Loccoz P, Karlin KD. Bhadra M, et al. Among authors: swart m. J Am Chem Soc. 2023 Feb 1;145(4):2230-2242. doi: 10.1021/jacs.2c09874. Epub 2023 Jan 18. J Am Chem Soc. 2023. PMID: 36652374 Free PMC article.

10

Catalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups.

Rajabimoghadam K, Darwish Y, Bashir U, Pitman D, Eichelberger S, Siegler MA, Swart M, Garcia-Bosch I. Rajabimoghadam K, et al. Among authors: swart m. J Am Chem Soc. 2018 Dec 5;140(48):16625-16634. doi: 10.1021/jacs.8b08748. Epub 2018 Nov 19. J Am Chem Soc. 2018. PMID: 30400740 Free PMC article.

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