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Dynamic metal coordination controls chemoselectivity in radical halogenases.
bioRxiv [Preprint]. 2024 Sep 20:2024.09.19.613983. doi: 10.1101/2024.09.19.613983.
bioRxiv. 2024.
PMID: 39345585
Free PMC article.
Preprint.
Experimental Evidence and Mechanistic Description of the Phenolic H-Transfer to the Cu2O2 Active Site of oxy-Tyrosinase.
Kipouros I, Stańczak A, Dunietz EM, Ginsbach JW, Srnec M, Rulíšek L, Solomon EI.
Kipouros I, et al.
J Am Chem Soc. 2023 Oct 25;145(42):22866-22870. doi: 10.1021/jacs.3c07450. Epub 2023 Oct 16.
J Am Chem Soc. 2023.
PMID: 37844210
Free PMC article.
Item in Clipboard
New mechanistic insights into coupled binuclear copper monooxygenases from the recent elucidation of the ternary intermediate of tyrosinase.
Kipouros I, Solomon EI.
Kipouros I, et al.
FEBS Lett. 2023 Jan;597(1):65-78. doi: 10.1002/1873-3468.14503. Epub 2022 Oct 6.
FEBS Lett. 2023.
PMID: 36178078
Free PMC article.
Review.
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Elucidation of the tyrosinase/O2/monophenol ternary intermediate that dictates the monooxygenation mechanism in melanin biosynthesis.
Kipouros I, Stańczak A, Ginsbach JW, Andrikopoulos PC, Rulíšek L, Solomon EI.
Kipouros I, et al.
Proc Natl Acad Sci U S A. 2022 Aug 16;119(33):e2205619119. doi: 10.1073/pnas.2205619119. Epub 2022 Aug 8.
Proc Natl Acad Sci U S A. 2022.
PMID: 35939688
Free PMC article.
Item in Clipboard
Evidence for H-bonding interactions to the μ-η2:η2-peroxide of oxy-tyrosinase that activate its coupled binuclear copper site.
Kipouros I, Stańczak A, Culka M, Andris E, Machonkin TR, Rulíšek L, Solomon EI.
Kipouros I, et al.
Chem Commun (Camb). 2022 Mar 22;58(24):3913-3916. doi: 10.1039/d2cc00750a.
Chem Commun (Camb). 2022.
PMID: 35237779
Free PMC article.
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Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates.
Diaz DE, Quist DA, Herzog AE, Schaefer AW, Kipouros I, Bhadra M, Solomon EI, Karlin KD.
Diaz DE, et al. Among authors: kipouros i.
Angew Chem Int Ed Engl. 2019 Dec 2;58(49):17572-17576. doi: 10.1002/anie.201908471. Epub 2019 Oct 23.
Angew Chem Int Ed Engl. 2019.
PMID: 31469942
Free PMC article.
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Oxidation of 5'-dGMP, 5'-dGDP, and 5'-dGTP by a platinum(IV) complex.
Kipouros I, Fica-Contreras SM, Bowe GJ, Choi S.
Kipouros I, et al.
J Biol Inorg Chem. 2015 Dec;20(8):1327-41. doi: 10.1007/s00775-015-1312-0. Epub 2015 Nov 21.
J Biol Inorg Chem. 2015.
PMID: 26588933
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