Geometric control of nuclearity in copper(I)/dioxygen chemistry.
Abe T, Morimoto Y, Tano T, Mieda K, Sugimoto H, Fujieda N, Ogura T, Itoh S.
Abe T, et al. Among authors: itoh s.
Inorg Chem. 2014 Aug 18;53(16):8786-94. doi: 10.1021/ic501461n. Epub 2014 Aug 7.
Inorg Chem. 2014.
PMID: 25101861
The copper(I) complex of L8 preferentially provided a mononuclear copper(II) end-on superoxide complex S as reported previously [Itoh, S., et al. J. Am. Chem. Soc. 2009, 131, 2788-2789], whereas a copper(I) complex of L7 gave a bis(mu-oxido)dicopper(III) comp …
The copper(I) complex of L8 preferentially provided a mononuclear copper(II) end-on superoxide complex S as reported previously [I …