Siegler MA - Search Results

1

Tuning the Thermochemistry and Reactivity of a Series of Cu-Based 4H⁺/4e^- Electron-Coupled-Proton Buffers.

Wu T, Puri A, Qiu YL, Ye D, Sarma R, Wang Y, Kowalewski T, Siegler MA, Swart M, Garcia-Bosch I. Wu T, et al. Among authors: siegler ma. Inorg Chem. 2024 May 20;63(20):9014-9025. doi: 10.1021/acs.inorgchem.4c00835. Epub 2024 May 9. Inorg Chem. 2024. PMID: 38723621 Free PMC article.

2

Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent.

Kim S, Saracini C, Siegler MA, Drichko N, Karlin KD. Kim S, et al. Among authors: siegler ma. Inorg Chem. 2012 Dec 3;51(23):12603-5. doi: 10.1021/ic302071e. Epub 2012 Nov 15. Inorg Chem. 2012. PMID: 23153187 Free PMC article.

3

Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity.

Garcia-Bosch I, Cowley RE, Díaz DE, Siegler MA, Nam W, Solomon EI, Karlin KD. Garcia-Bosch I, et al. Among authors: siegler ma. Chemistry. 2016 Apr 4;22(15):5133-7. doi: 10.1002/chem.201600551. Epub 2016 Feb 26. Chemistry. 2016. PMID: 26919169 Free PMC article.

4

The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities.

Joslin EE, Zaragoza JP, Baglia RA, Siegler MA, Goldberg DP. Joslin EE, et al. Among authors: siegler ma. Inorg Chem. 2016 Sep 6;55(17):8646-60. doi: 10.1021/acs.inorgchem.6b01219. Epub 2016 Aug 16. Inorg Chem. 2016. PMID: 27529361 Free PMC article.

5

Copper-Catalyzed Oxidation of Alkanes with H2 O2 under a Fenton-like Regime.

Garcia-Bosch I, Siegler MA. Garcia-Bosch I, et al. Among authors: siegler ma. Angew Chem Int Ed Engl. 2016 Oct 4;55(41):12873-6. doi: 10.1002/anie.201607216. Epub 2016 Sep 9. Angew Chem Int Ed Engl. 2016. PMID: 27610603

6

Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.

Adam SM, Garcia-Bosch I, Schaefer AW, Sharma SK, Siegler MA, Solomon EI, Karlin KD. Adam SM, et al. Among authors: siegler ma. J Am Chem Soc. 2017 Jan 11;139(1):472-481. doi: 10.1021/jacs.6b11322. Epub 2016 Dec 28. J Am Chem Soc. 2017. PMID: 28029788 Free PMC article.

7

Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp³ C-H Bonds.

Trammell R, See YY, Herrmann AT, Xie N, Díaz DE, Siegler MA, Baran PS, Garcia-Bosch I. Trammell R, et al. Among authors: siegler ma. J Org Chem. 2017 Aug 4;82(15):7887-7904. doi: 10.1021/acs.joc.7b01069. Epub 2017 Jul 14. J Org Chem. 2017. PMID: 28654755 Free PMC article.

8

Catalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups.

Rajabimoghadam K, Darwish Y, Bashir U, Pitman D, Eichelberger S, Siegler MA, Swart M, Garcia-Bosch I. Rajabimoghadam K, et al. Among authors: siegler ma. J Am Chem Soc. 2018 Dec 5;140(48):16625-16634. doi: 10.1021/jacs.8b08748. Epub 2018 Nov 19. J Am Chem Soc. 2018. PMID: 30400740 Free PMC article.

9

Directed Hydroxylation of sp² and sp³ C-H Bonds Using Stoichiometric Amounts of Cu and H₂O₂.

Trammell R, D'Amore L, Cordova A, Polunin P, Xie N, Siegler MA, Belanzoni P, Swart M, Garcia-Bosch I. Trammell R, et al. Among authors: siegler ma. Inorg Chem. 2019 Jun 3;58(11):7584-7592. doi: 10.1021/acs.inorgchem.9b00901. Epub 2019 May 14. Inorg Chem. 2019. PMID: 31084018 Free PMC article.

10

Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States.

Wu T, MacMillan SN, Rajabimoghadam K, Siegler MA, Lancaster KM, Garcia-Bosch I. Wu T, et al. Among authors: siegler ma. J Am Chem Soc. 2020 Jul 15;142(28):12265-12276. doi: 10.1021/jacs.0c03867. Epub 2020 Jul 1. J Am Chem Soc. 2020. PMID: 32531159 Free PMC article.

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