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Gas-free alkoxycarbonylation of aryl iodides in a phosphonium-based deep eutectic solvent with Mo(CO)₆ as a solid CO source.

Messa F, Paparella AN, Perrone S, Salomone A. Messa F, et al. Among authors: paparella an. Org Biomol Chem. 2023 Jun 28;21(25):5164-5170. doi: 10.1039/d3ob00596h. Org Biomol Chem. 2023. PMID: 37283189

A phosphonium-based deep eutectic solvent promotes the stereoselective semi-reduction of internal alkynes to (Z)-alkenes.

Paparella AN, Messa F, Perrone S, Salomone A. Paparella AN, et al. Org Biomol Chem. 2023 May 10;21(18):3770-3777. doi: 10.1039/d3ob00433c. Org Biomol Chem. 2023. PMID: 37078606

An enhanced stereoselective synthesis of α,β-unsaturated esters through the Horner-Wadsworth-Emmons reaction in deep eutectic solvents.

Paparella AN, Stallone M, Pulpito M, Perna FM, Capriati V, Vitale P. Paparella AN, et al. Org Biomol Chem. 2024 Feb 28;22(9):1885-1891. doi: 10.1039/d3ob02083e. Org Biomol Chem. 2024. PMID: 38349132

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