Frontier AJ - Search Results

1

Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the halo-Nazarov Cyclization.

Alachouzos G, Holt C, Frontier AJ. Alachouzos G, et al. Among authors: frontier aj. Org Lett. 2020 May 15;22(10):4010-4015. doi: 10.1021/acs.orglett.0c01330. Epub 2020 Apr 30. Org Lett. 2020. PMID: 32352794

2

A general method for the catalytic nazarov cyclization of heteroaromatic compounds.

Malona JA, Colbourne JM, Frontier AJ. Malona JA, et al. Among authors: frontier aj. Org Lett. 2006 Nov 23;8(24):5661-4. doi: 10.1021/ol062403v. Org Lett. 2006. PMID: 17107097

3

Formal synthesis of (+/-)-roseophilin.

Bitar AY, Frontier AJ. Bitar AY, et al. Among authors: frontier aj. Org Lett. 2009 Jan 1;11(1):49-52. doi: 10.1021/ol802329y. Org Lett. 2009. PMID: 19053717 Free PMC article.

4

Oxidation-initiated Nazarov cyclization of vinyl alkoxyallenes.

Spencer WT 3rd, Levin MD, Frontier AJ. Spencer WT 3rd, et al. Among authors: frontier aj. Org Lett. 2011 Feb 4;13(3):414-7. doi: 10.1021/ol1027255. Epub 2010 Dec 14. Org Lett. 2011. PMID: 21155592 Free PMC article.

5

Total synthesis of (±)-rocaglamide via oxidation-initiated Nazarov cyclization.

Malona JA, Cariou K, Spencer WT 3rd, Frontier AJ. Malona JA, et al. Among authors: frontier aj. J Org Chem. 2012 Feb 17;77(4):1891-908. doi: 10.1021/jo202366c. Epub 2012 Jan 26. J Org Chem. 2012. PMID: 22283818 Free PMC article.

6

A macrocyclic β-iodoallenolate intermediate is key: synthesis of the ABD core of phomactin A.

Ciesielski J, Cariou K, Frontier AJ. Ciesielski J, et al. Among authors: frontier aj. Org Lett. 2012 Aug 17;14(16):4082-5. doi: 10.1021/ol3017116. Epub 2012 Aug 2. Org Lett. 2012. PMID: 22853449 Free PMC article.

7

Cationic cyclizations and rearrangements promoted by a heterogeneous gold catalyst.

Vaidya T, Cheng R, Carlsen PN, Frontier AJ, Eisenberg R. Vaidya T, et al. Among authors: frontier aj. Org Lett. 2014 Feb 7;16(3):800-3. doi: 10.1021/ol403542k. Epub 2014 Jan 16. Org Lett. 2014. PMID: 24432741 Free PMC article.

8

Enantioselective Nazarov Cyclization Catalyzed by a Cinchona Alkaloid Derivative.

Huang YW, Frontier AJ. Huang YW, et al. Among authors: frontier aj. Tetrahedron Lett. 2015 Jun 3;56(23):3523-3526. doi: 10.1016/j.tetlet.2014.12.136. Tetrahedron Lett. 2015. PMID: 26085696 Free PMC article.

9

Nazarov Cyclization/Internal Redox Cyclization Sequence for the Synthesis of N-Heterocyclic Bridged Ring Systems.

Huang YW, Frontier AJ. Huang YW, et al. Among authors: frontier aj. Org Lett. 2016 Oct 7;18(19):4896-4899. doi: 10.1021/acs.orglett.6b02369. Epub 2016 Sep 21. Org Lett. 2016. PMID: 27652822

10

Diastereoselective Construction of Densely Functionalized 1-Halocyclopentenes Using an Alkynyl Halo-Prins/Halo-Nazarov Cyclization Strategy.

Alachouzos G, Frontier AJ. Alachouzos G, et al. Among authors: frontier aj. Angew Chem Int Ed Engl. 2017 Nov 20;56(47):15030-15034. doi: 10.1002/anie.201709482. Epub 2017 Oct 24. Angew Chem Int Ed Engl. 2017. PMID: 29065241

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