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Reference scales for the characterization of cationic electrophiles and neutral nucleophiles.
Mayr H, Bug T, Gotta MF, Hering N, Irrgang B, Janker B, Kempf B, Loos R, Ofial AR, Remennikov G, Schimmel H. Mayr H, et al. J Am Chem Soc. 2001 Oct 3;123(39):9500-12. doi: 10.1021/ja010890y. J Am Chem Soc. 2001. PMID: 11572670
The rate constants of 209 combinations of these benzhydrylium ions and pi-nucleophiles, 85 of which are first presented in this article, have been subjected to a correlation analysis to determine the electrophilicity parameters E and the nucleophilicity parameters N and s as defi …
The rate constants of 209 combinations of these benzhydrylium ions and pi-nucleophiles, 85 of which are first presented in this article, hav …
Relationships between carbocation stabilities and electrophilic reactivity parameters, E: quantum mechanical studies of benzhydryl cation structures and stabilities.
Schindele C, Houk KN, Mayr H. Schindele C, et al. Among authors: mayr h. J Am Chem Soc. 2002 Sep 18;124(37):11208-14. doi: 10.1021/ja020617b. J Am Chem Soc. 2002. PMID: 12224969

An excellent linear correlation between the empirical electrophilicity parameter E (by log k = s(N + E); Mayr, H.; Bug, T.; Gotta, M. F.; Hering, N.; Irrgang, B.; Janker, B.; Kempf, B.; Loos, R.; Ofial, A. ...On the other hand, a value of s < or = 0.67 as found f

…
An excellent linear correlation between the empirical electrophilicity parameter E (by log k = s(N + E); Mayr, H.; Bug, T.; Go …
Solvent nucleophilicity.
Minegishi S, Kobayashi S, Mayr H. Minegishi S, et al. Among authors: mayr h. J Am Chem Soc. 2004 Apr 28;126(16):5174-81. doi: 10.1021/ja031828z. J Am Chem Soc. 2004. PMID: 15099100
457 results