Fernández-Alvarez FJ - Search Results

1

Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe₂Ph catalyzed by iridium complexes.

Guzmán J , Bernal AM , García-Orduña P , Lahoz FJ , Oro LA , Fernández-Alvarez FJ . Guzmán J , et al. Dalton Trans. 2019 Mar 26;48(13):4255-4262. doi: 10.1039/c8dt05070h. Dalton Trans. 2019. PMID: 30847452

2

A synthon for a 14-electron Ir(III) species: catalyst for highly selective β-(Z) hydrosilylation of terminal alkynes.

Iglesias M, Pérez-Nicolás M, Sanz Miguel PJ, Polo V, Fernández-Alvarez FJ, Pérez-Torrente JJ, Oro LA. Iglesias M, et al. Chem Commun (Camb). 2012 Oct 4;48(76):9480-2. doi: 10.1039/c2cc34931k. Chem Commun (Camb). 2012. PMID: 22903436

3

Effective fixation of CO2 by iridium-catalyzed hydrosilylation.

Lalrempuia R, Iglesias M, Polo V, Sanz Miguel PJ, Fernández-Alvarez FJ, Pérez-Torrente JJ, Oro LA. Lalrempuia R, et al. Angew Chem Int Ed Engl. 2012 Dec 14;51(51):12824-7. doi: 10.1002/anie.201206165. Epub 2012 Sep 14. Angew Chem Int Ed Engl. 2012. PMID: 22987477 No abstract available.

4

An alternative mechanistic paradigm for the β-Z hydrosilylation of terminal alkynes: the role of acetone as a silane shuttle.

Iglesias M, Sanz Miguel PJ, Polo V, Fernández-Alvarez FJ, Pérez-Torrente JJ, Oro LA. Iglesias M, et al. Chemistry. 2013 Dec 16;19(51):17559-66. doi: 10.1002/chem.201303063. Epub 2013 Nov 14. Chemistry. 2013. PMID: 24243515

5

Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts.

Lázaro G, Polo V, Fernández-Alvarez FJ, García-Orduña P, Lahoz FJ, Iglesias M, Pérez-Torrente JJ, Oro LA. Lázaro G, et al. ChemSusChem. 2015 Feb;8(3):495-503. doi: 10.1002/cssc.201403036. Epub 2014 Dec 10. ChemSusChem. 2015. PMID: 25504980

6

Rhodium-Catalyzed Dehydrogenative Silylation of Acetophenone Derivatives: Formation of Silyl Enol Ethers versus Silyl Ethers.

Garcés K, Lalrempuia R, Polo V, Fernández-Alvarez FJ, García-Orduña P, Lahoz FJ, Pérez-Torrente JJ, Oro LA. Garcés K, et al. Chemistry. 2016 Oct 4;22(41):14717-29. doi: 10.1002/chem.201602760. Epub 2016 Aug 24. Chemistry. 2016. PMID: 27553810

7

Mechanistic Insights on the Reduction of CO₂ to Silylformates Catalyzed by Ir-NSiN Species.

Julián A, Guzmán J, Jaseer EA, Fernández-Alvarez FJ, Royo R, Polo V, García-Orduña P, Lahoz FJ, Oro LA. Julián A, et al. Chemistry. 2017 Sep 4;23(49):11898-11907. doi: 10.1002/chem.201702246. Epub 2017 Aug 9. Chemistry. 2017. PMID: 28644915

8

Synthesis and reactivity at the Ir-^MeTpm platform: from κ¹-N coordination to κ³-N-based organometallic chemistry.

Fernández-Alvarez FJ, Polo V, García-Orduña P, Lahoz FJ, Pérez-Torrente JJ, Oro LA, Lalrempuia R. Fernández-Alvarez FJ, et al. Dalton Trans. 2019 May 15;48(19):6455-6463. doi: 10.1039/c9dt00703b. Dalton Trans. 2019. PMID: 30924485

9

2-Pyridone-stabilized iridium silylene/silyl complexes: structure and QTAIM analysis.

Guzmán J , Bernal AM , García-Orduña P , Lahoz FJ , Polo V , Fernández-Alvarez FJ . Guzmán J , et al. Dalton Trans. 2020 Dec 22;49(48):17665-17673. doi: 10.1039/d0dt03326j. Dalton Trans. 2020. PMID: 33232415

10

Origin of the Ir-Si bond shortening in Ir-NSiN complexes.

García-Orduña P, Fernández I, Oro LA, Fernández-Alvarez FJ. García-Orduña P, et al. Among authors: fernandez alvarez fj. Dalton Trans. 2021 May 4;50(17):5951-5959. doi: 10.1039/d1dt00473e. Dalton Trans. 2021. PMID: 33949537

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