Shearer J - Search Results

1

Reduction of CO₂ by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate.

Roy L, Al-Afyouni MH, DeRosha DE, Mondal B, DiMucci IM, Lancaster KM, Shearer J, Bill E, Brennessel WW, Neese F, Ye S, Holland PL. Roy L, et al. Among authors: shearer j. Chem Sci. 2018 Nov 9;10(3):918-929. doi: 10.1039/c8sc02599a. eCollection 2019 Jan 21. Chem Sci. 2018. PMID: 30774886 Free PMC article.

2

Chalcogen Impact on Covalency within Molecular [Cu₃(μ₃-E)]³⁺ Clusters (E = O, S, Se): A Synthetic, Spectroscopic, and Computational Study.

Cook BJ, Di Francesco GN, Ferreira RB, Lukens JT, Silberstein KE, Keegan BC, Catalano VJ, Lancaster KM, Shearer J, Murray LJ. Cook BJ, et al. Among authors: shearer j. Inorg Chem. 2018 Sep 17;57(18):11382-11392. doi: 10.1021/acs.inorgchem.8b01000. Epub 2018 Aug 30. Inorg Chem. 2018. PMID: 30160943 Free PMC article.

3

Bonding and the role of electrostatics in driving C-C bond formation in high valent organocopper compounds.

Shearer J, Vasiliauskas D, Lancaster KM. Shearer J, et al. Chem Commun (Camb). 2022 Dec 22;59(1):98-101. doi: 10.1039/d2cc05865k. Chem Commun (Camb). 2022. PMID: 36472142 Free PMC article.

4

Scrutinizing formally Ni^IV centers through the lenses of core spectroscopy, molecular orbital theory, and valence bond theory.

DiMucci IM, Titus CJ, Nordlund D, Bour JR, Chong E, Grigas DP, Hu CH, Kosobokov MD, Martin CD, Mirica LM, Nebra N, Vicic DA, Yorks LL, Yruegas S, MacMillan SN, Shearer J, Lancaster KM. DiMucci IM, et al. Among authors: shearer j. Chem Sci. 2023 Jun 9;14(25):6915-6929. doi: 10.1039/d3sc02001k. eCollection 2023 Jun 28. Chem Sci. 2023. PMID: 37389249 Free PMC article.

5

The Oxo-Wall Remains Intact: A Tetrahedrally Distorted Co(IV)-Oxo Complex.

Yang J, Dong HT, Seo MS, Larson VA, Lee YM, Shearer J, Lehnert N, Nam W. Yang J, et al. Among authors: shearer j. J Am Chem Soc. 2021 Oct 20;143(41):16943-16959. doi: 10.1021/jacs.1c04919. Epub 2021 Oct 5. J Am Chem Soc. 2021. PMID: 34609879

6

Scaffold-based [Fe]-hydrogenase model: H₂ activation initiates Fe(0)-hydride extrusion and non-biomimetic hydride transfer.

Kerns SA, Seo J, Lynch VM, Shearer J, Goralski ST, Sullivan ER, Rose MJ. Kerns SA, et al. Among authors: shearer j. Chem Sci. 2021 Sep 10;12(38):12838-12846. doi: 10.1039/d0sc03154b. eCollection 2021 Oct 6. Chem Sci. 2021. PMID: 34703571 Free PMC article.

7

Preparation and Characterization of a Formally Ni^IV-Oxo Complex with a Triplet Ground State and Application in Oxidation Reactions.

Karmalkar DG, Larson VA, Malik DD, Lee YM, Seo MS, Kim J, Vasiliauskas D, Shearer J, Lehnert N, Nam W. Karmalkar DG, et al. Among authors: shearer j. J Am Chem Soc. 2022 Dec 14;144(49):22698-22712. doi: 10.1021/jacs.2c10196. Epub 2022 Dec 1. J Am Chem Soc. 2022. PMID: 36454200

8

Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an Unusual S = 3/2 Ground State that Promotes N-Group and Hydrogen Atom-Transfer Reactions with Exogenous Substrates.

Yang J, Tripodi GL, Derks MTGM, Seo MS, Lee YM, Southwell KW, Shearer J, Roithová J, Nam W. Yang J, et al. Among authors: shearer j. J Am Chem Soc. 2023 Dec 6;145(48):26106-26121. doi: 10.1021/jacs.3c08117. Epub 2023 Nov 24. J Am Chem Soc. 2023. PMID: 37997643 Free PMC article.

9

Structure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene Complex.

Yang J, Seo MS, Kim KH, Lee YM, Fukuzumi S, Shearer J, Nam W. Yang J, et al. Among authors: shearer j. Angew Chem Int Ed Engl. 2020 Aug 3;59(32):13581-13585. doi: 10.1002/anie.202005091. Epub 2020 May 26. Angew Chem Int Ed Engl. 2020. PMID: 32358999

10

pH Dependent Reversible Formation of a Binuclear Ni₂ Metal-Center Within a Peptide Scaffold.

Keegan BC, Ocampo D, Shearer J. Keegan BC, et al. Among authors: shearer j. Inorganics (Basel). 2019 Jul;7(7):90. doi: 10.3390/inorganics7070090. Epub 2019 Jul 16. Inorganics (Basel). 2019. PMID: 38046130 Free PMC article.

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