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Reference scales for the characterization of cationic electrophiles and neutral nucleophiles.
Mayr H, Bug T, Gotta MF, Hering N, Irrgang B, Janker B, Kempf B, Loos R, Ofial AR, Remennikov G, Schimmel H. Mayr H, et al. J Am Chem Soc. 2001 Oct 3;123(39):9500-12. doi: 10.1021/ja010890y. J Am Chem Soc. 2001. PMID: 11572670
The rate constants of 209 combinations of these benzhydrylium ions and pi-nucleophiles, 85 of which are first presented in this article, have been subjected to a correlation analysis to determine the electrophilicity parameters E and the nucleophilicity parameters N and s as defi …
The rate constants of 209 combinations of these benzhydrylium ions and pi-nucleophiles, 85 of which are first presented in this article, hav …
How nucleophilic are diazo compounds?
Bug T, Hartnagel M, Schlierf C, Mayr H. Bug T, et al. Among authors: mayr h. Chemistry. 2003 Sep 5;9(17):4068-76. doi: 10.1002/chem.200304913. Chemistry. 2003. PMID: 12953192
How fast do R-X bonds ionize? A semiquantitative approach.
Denegri B, Ofial AR, Jurić S, Streiter A, Kronja O, Mayr H. Denegri B, et al. Among authors: mayr h. Chemistry. 2006 Feb 8;12(6):1657-66. doi: 10.1002/chem.200500847. Chemistry. 2006. PMID: 16331713
457 results