Stereochemistry during aflatoxin biosynthesis: cyclase reaction in the conversion of versiconal to versicolorin B and racemization of versiconal hemiacetal acetate.
Yabe K, Hamasaki T.
Yabe K, et al. Among authors: hamasaki t.
Appl Environ Microbiol. 1993 Aug;59(8):2493-500. doi: 10.1128/aem.59.8.2493-2500.1993.
Appl Environ Microbiol. 1993.
PMID: 8368837
Free PMC article.
(1'R,2'S)-(-)-aflatoxins are produced from racemic versiconal hemiacetal acetate (VHA) through complicated pathways, including a metabolic grid involving VHA, versiconol acetate (VOAc), versiconol, and versiconal (VHOH), and a reaction sequence from VHOH to versicolorin A (VA) th …
(1'R,2'S)-(-)-aflatoxins are produced from racemic versiconal hemiacetal acetate (VHA) through complicated pathways, including a metabolic g …