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Reversible CO binding enables tunable CO/H₂ and CO/N₂ separations in metal-organic frameworks with exposed divalent metal cations.
Bloch ED, Hudson MR, Mason JA, Chavan S, Crocellà V, Howe JD, Lee K, Dzubak AL, Queen WL, Zadrozny JM, Geier SJ, Lin LC, Gagliardi L, Smit B, Neaton JB, Bordiga S, Brown CM, Long JR. Bloch ED, et al. Among authors: geier sj. J Am Chem Soc. 2014 Jul 30;136(30):10752-61. doi: 10.1021/ja505318p. Epub 2014 Jul 18. J Am Chem Soc. 2014. PMID: 24999916
M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) metal-organic frameworks exhibiting increased charge density and enhanced H2 binding at the open metal sites.
Kapelewski MT, Geier SJ, Hudson MR, Stück D, Mason JA, Nelson JN, Xiao DJ, Hulvey Z, Gilmour E, FitzGerald SA, Head-Gordon M, Brown CM, Long JR. Kapelewski MT, et al. Among authors: geier sj. J Am Chem Soc. 2014 Aug 27;136(34):12119-29. doi: 10.1021/ja506230r. Epub 2014 Aug 18. J Am Chem Soc. 2014. PMID: 25130365 Free article.
Activation of H2 by phosphinoboranes R2PB(C6F5)2.
Geier SJ, Gilbert TM, Stephan DW. Geier SJ, et al. J Am Chem Soc. 2008 Sep 24;130(38):12632-3. doi: 10.1021/ja805493y. Epub 2008 Aug 28. J Am Chem Soc. 2008. PMID: 18754584
Rh-catalyzed P-P bond activation.
Geier SJ, Stephan DW. Geier SJ, et al. Chem Commun (Camb). 2008 Jan 7;(1):99-101. doi: 10.1039/b712972f. Chem Commun (Camb). 2008. PMID: 18399413
30 results