Compounds with a 'stuffed' anti-bixbyite-type structure, analysed in terms of the Zintl-Klemm and coordination-defect concepts.
Vegas A, Martin RL, Bevan DJ.
Vegas A, et al.
Acta Crystallogr B. 2009 Feb;65(Pt 1):11-21. doi: 10.1107/S010876810803423X. Epub 2008 Dec 20.
Acta Crystallogr B. 2009.
PMID: 19155554
Free PMC article.
The bixbyite structure (Mn(2)O(3)) (Ia3) is often described as a distorted face-centered cubic (f.c.c.) array of Mn atoms, with O atoms occupying 3/4 of the tetrahedral holes. ...The presence of these atoms in 16c is illuminated in the light of the extended Zintl-Klemm con …
The bixbyite structure (Mn(2)O(3)) (Ia3) is often described as a distorted face-centered cubic (f.c.c.) array of Mn atoms, with O ato …