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Detailed structural investigation of the grafting of [Ta(=CHtBu)(CH2tBu)3] and [Cp*TaMe4] on silica partially dehydroxylated at 700 degrees C and the activity of the grafted complexes toward alkane metathesis.
Le Roux E, Chabanas M, Baudouin A, de Mallmann A, Copéret C, Quadrelli EA, Thivolle-Cazat J, Basset JM, Lukens W, Lesage A, Emsley L, Sunley GJ. Le Roux E, et al. J Am Chem Soc. 2004 Oct 20;126(41):13391-9. doi: 10.1021/ja046486r. J Am Chem Soc. 2004. PMID: 15479095
Primary products and mechanistic considerations in alkane metathesis.
Basset JM, Copéret C, Lefort L, Maunders BM, Maury O, Le Roux E, Saggio G, Soignier S, Soulivong D, Sunley GJ, Taoufik M, Thivolle-Cazat J. Basset JM, et al. Among authors: le roux e. J Am Chem Soc. 2005 Jun 22;127(24):8604-5. doi: 10.1021/ja051679f. J Am Chem Soc. 2005. PMID: 15954760
[(≡SiO)Ta(V)Cl2Me2]: a well-defined silica-supported tantalum(V) surface complex as catalyst precursor for the selective cocatalyst-free trimerization of ethylene.
Chen Y, Callens E, Abou-Hamad E, Merle N, White AJ, Taoufik M, Copéret C, Le Roux E, Basset JM. Chen Y, et al. Among authors: le roux e. Angew Chem Int Ed Engl. 2012 Nov 19;51(47):11886-9. doi: 10.1002/anie.201206272. Epub 2012 Oct 22. Angew Chem Int Ed Engl. 2012. PMID: 23090868 No abstract available.
136 results