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Reference scales for the characterization of cationic electrophiles and neutral nucleophiles.
Mayr H, Bug T, Gotta MF, Hering N, Irrgang B, Janker B, Kempf B, Loos R, Ofial AR, Remennikov G, Schimmel H. Mayr H, et al. J Am Chem Soc. 2001 Oct 3;123(39):9500-12. doi: 10.1021/ja010890y. J Am Chem Soc. 2001. PMID: 11572670
The rate constants of 209 combinations of these benzhydrylium ions and pi-nucleophiles, 85 of which are first presented in this article, have been subjected to a correlation analysis to determine the electrophilicity parameters E and the nucleophilicity parameters N and s as defi …
The rate constants of 209 combinations of these benzhydrylium ions and pi-nucleophiles, 85 of which are first presented in this article, hav …
S(N)1 reactions with inverse rate profiles.
Denegri B, Minegishi S, Kronja O, Mayr H. Denegri B, et al. Among authors: mayr h. Angew Chem Int Ed Engl. 2004 Apr 19;43(17):2302-5. doi: 10.1002/anie.200353468. Angew Chem Int Ed Engl. 2004. PMID: 15108152 No abstract available.
How fast do R-X bonds ionize? A semiquantitative approach.
Denegri B, Ofial AR, Jurić S, Streiter A, Kronja O, Mayr H. Denegri B, et al. Among authors: mayr h. Chemistry. 2006 Feb 8;12(6):1657-66. doi: 10.1002/chem.200500847. Chemistry. 2006. PMID: 16331713
Nucleophilic reactivities of indoles.
Lakhdar S, Westermaier M, Terrier F, Goumont R, Boubaker T, Ofial AR, Mayr H. Lakhdar S, et al. Among authors: mayr h. J Org Chem. 2006 Nov 24;71(24):9088-95. doi: 10.1021/jo0614339. J Org Chem. 2006. PMID: 17109534
457 results