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A palladium-oxo complex. Stabilization of this proposed catalytic intermediate by an encapsulating polytungstate ligand.
Anderson TM, Cao R, Slonkina E, Hedman B, Hodgson KO, Hardcastle KI, Neiwert WA, Wu S, Kirk ML, Knottenbelt S, Depperman EC, Keita B, Nadjo L, Musaev DG, Morokuma K, Hill CL. Anderson TM, et al. Among authors: depperman ec. J Am Chem Soc. 2005 Aug 31;127(34):11948-9. doi: 10.1021/ja054131h. J Am Chem Soc. 2005. Retraction in: J Am Chem Soc. 2012 Jun 6;134(22):9533. doi: 10.1021/ja207910h PMID: 16117527 Retracted.
Revisiting the polyoxometalate-based late-transition-metal-oxo complexes: the "oxo wall" stands.
O'Halloran KP, Zhao C, Ando NS, Schultz AJ, Koetzle TF, Piccoli PM, Hedman B, Hodgson KO, Bobyr E, Kirk ML, Knottenbelt S, Depperman EC, Stein B, Anderson TM, Cao R, Geletii YV, Hardcastle KI, Musaev DG, Neiwert WA, Fang X, Morokuma K, Wu S, Kögerler P, Hill CL. O'Halloran KP, et al. Among authors: depperman ec. Inorg Chem. 2012 Jul 2;51(13):7025-31. doi: 10.1021/ic2008914. Epub 2012 Jun 13. Inorg Chem. 2012. PMID: 22694272
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