Gmelinosides A-L, twelve acylated iridoid glycosides from Gmelina arborea

J Nat Prod. 1998 Jun 26;61(6):734-42. doi: 10.1021/np970447u.

Abstract

Besides the known iridoids 6-O-alpha-L-rhamnopyranosylcatalpol (1), 6-O-(3"-O-trans-feruloyl)-alpha-L-rhamnopyranosylcatalpol (14), 6-O-(2"-O-acetyl-3", 4"-O-di-trans-cinnamoyl)-alpha-L-rhamnopyranosylcatalpol (15) and the known phenylpropanoid glycosides verbascoside (acteoside) and martynoside, 12 new acylated iridoid glycosides named gmelinosides A-L (2-13) have been isolated from the leaves of Gmelina arborea. These compounds were structurally characterized using a variety of spectral methods.

MeSH terms

  • Carbohydrate Sequence
  • Glycosides / chemistry*
  • Glycosides / isolation & purification
  • India
  • Magnetic Resonance Spectroscopy
  • Molecular Sequence Data
  • Plants, Medicinal / chemistry*
  • Spectrometry, Mass, Fast Atom Bombardment
  • Spectrophotometry, Infrared
  • Spectrophotometry, Ultraviolet

Substances

  • Glycosides