Specificity of the N1 and N2 sialidase subtypes of human influenza A virus for natural and synthetic gangliosides

Glycobiology. 1998 Jun;8(6):527-32. doi: 10.1093/glycob/8.6.527.

Abstract

Sialyl-linkage specificity of sialidases of the human influenza A virus strains, A/Aichi/2/68 (H3N2) and A/PR/8/34 (H1N1) were studied using natural and synthetic gangliosides. The sialidase of the A/Aichi/2/68 strain hydrolyzed the terminal Neu5Acalpha2-3Gal sequence but not the Neu5Acalpha2-3 linkage on the inner Gal of GM1a, which is a ganglioside that has the gangliotetraose chain (Galbeta1-3GalNAcbeta1-4-(Neu5Acalpha2-3)Galbeta1++ +-4Glcbeta1-Cer). The sialidase hydrolyzed the Neu5Ac on the inner Gal of GM2, which had a shorter gangliotriose chain. GM4, which had the shortest chain (Neu5Acalpha2-3Galbeta1-Cer) of the gangliosides, had a lower substrate specificity. The N1 and N2 sialidase subtypes of the human influenza A virus had no significant variation in their substrate specificity for the gangliosides. Analysis of 11 synthetic gangliosides, which contained various ceramide or sialic acid moieties, demonstrated that A/Aichi/2/68 (H3N2) sialidase recognized the ceramide and sialic acid moiety and the length and structure of the sialyl sugar chain.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbohydrate Sequence
  • Gangliosides / chemical synthesis
  • Gangliosides / metabolism*
  • Humans
  • Influenza A virus / chemistry
  • Influenza A virus / enzymology*
  • Isoenzymes / metabolism*
  • Molecular Sequence Data
  • Neuraminidase / metabolism*
  • Substrate Specificity

Substances

  • Gangliosides
  • Isoenzymes
  • Neuraminidase