The use of an atomic emission detector following a process of preconcentration of drinking water samples by a factor of 1500:1 allows the highly selective determination of chlorophenols present in samples below the maximum limit of 0.5 ng/ml set by international regulations. The preconcentration of the samples is carried out using 0.25-g commercial graphitized carbon cartridges without the need for sample derivatization prior to solid-phase extraction.