Abstract
Symmetric binding of nitrite via both O atoms to CuI [Cu--O = 2.191 (4) A] was observed. The copper coordination geometry is significantly distorted from tetrahedral, as evidenced by the angles P--Cu--P [127.75 (7) degrees] and O--Cu--O [56.7 (2) degrees].
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Crystallography, X-Ray
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Models, Molecular
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Organometallic Compounds / chemistry*
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Organophosphorus Compounds / chemistry*
Substances
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(nitrito-O,O')bis(triphenylphosphine)copper(I)
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Organometallic Compounds
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Organophosphorus Compounds