Induced chemiluminescence of oxidized fatty acids and oils

Lipids. 1985 Nov;20(11):729-34. doi: 10.1007/BF02534395.

Abstract

The injection of a strong organic base into milligram quantities of fats and oils dissolved in methylene chloride results in a burst of chemiluminescence whose peak intensity is a function of the previous thermal oxidation history and of the degree of unsaturation of the starting material. The flash of this induced chemiluminescence can be 10(8) times higher than the steady-state "spontaneous" chemiluminescence. The kinetics of the induced chemiluminescence are first order in concentration and second order in time. The emission spectrum is broad and extends into the near infrared. A model based on dioxetane chemiluminescence is proposed to explain the observed kinetics.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Fatty Acids / analysis*
  • Hot Temperature
  • Luminescent Measurements
  • Oils / analysis*
  • Oxidation-Reduction
  • Structure-Activity Relationship

Substances

  • Fatty Acids
  • Oils