Toward mechanistic understanding of wettability alteration in carbonate rocks in the presence of nanoparticles, gelatin biopolymer, and core-shell nanocomposite of Fe3O4@gelatin

Mohammad Ebrahimi; Hossein Ghalenavi; Mahin Schaffie; Mohammad Ranjbar; Abdolhossein Hemmati-Sarapardeh

doi:10.1038/s41598-024-80893-2

Toward mechanistic understanding of wettability alteration in carbonate rocks in the presence of nanoparticles, gelatin biopolymer, and core-shell nanocomposite of Fe₃O₄@gelatin

Sci Rep. 2024 Dec 30;14(1):31679. doi: 10.1038/s41598-024-80893-2.

Authors

Mohammad Ebrahimi¹, Hossein Ghalenavi¹, Mahin Schaffie¹, Mohammad Ranjbar¹, Abdolhossein Hemmati-Sarapardeh^{2

3}

Affiliations

¹ Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran.
² Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran. hemmati@uk.ac.ir.
³ Key Laboratory of Continental Shale Hydrocarbon Accumulation and Efficient Development, Ministry of Education, Northeast Petroleum University, Daqing, 163318, China. hemmati@uk.ac.ir.

Abstract

Because a significant portion of oil remains in carbonate reservoirs, efficient techniques are essential to increase oil recovery from carbonate reservoirs. Wettability alteration is crucial for enhanced oil recovery (EOR) from oil-wet reservoirs. This study investigates the impact of different substances on the wettability of dolomite and calcite rocks. The substances include silicon dioxide (SiO₂) and iron oxide (Fe₃O₄) nanofluids, gelatin biopolymer, surfactants (sodium dodecyl sulfate (SDS)), Fe₃O₄/SDS, seawater, and salt solutions (sodium chloride (NaCl) and calcium chloride (CaCl₂)). Initially, water-wet rocks were exposed to crude oil for 22 days, resulting in significant contact angle changes. Dolomite and calcite contact angles increased from 56.50° and 50.70° to 107.70° and 104.00°, respectively, due to the presence of heavy and polar elements in the oil. The impact of aging time (7 and 11 days) on rock wettability was studied. Oil-wet rocks were treated with SiO₂ and Fe₃O₄ nanofluids and SDS surfactants for 11 days. The contact angles of the treated rocks decreased significantly. For instance, the contact angles of dolomite and calcite treated with SDS surfactants decreased to 39.07° and 27.38°, respectively, indicating water-wet conditions. Dolomite and calcite surfaces aged with gelatin decreased the contact angles to 38.40° and 34.52°, respectively. Treatment with SiO₂ nanofluid reduced the contact angles of dolomite and calcite to 54.27° and 53.17°, respectively, while treatment with Fe₃O₄ nanofluid decreased the contact angles to 46.08° and 51.16°, respectively. Using Fe₃O₄/gelatin nanocomposite resulted in contact angles of 26.00° for dolomite and 24.10° for calcite. The wettability alteration mechanism in nanofluids is attributed to structural disjoining pressure. Additionally, NaCl and CaCl₂ solutions induced water-wet conditions, known as the salting-out effect, on dolomite and calcite specimens. Consequently, this study demonstrates the potential of various substances, such as nanofluids, surfactants, and salt solutions, to modify rock wettability and improve conditions for enhanced oil recovery.

Keywords: Calcite and Dolomite rock; Contact angle; Fe3O4 and SiO2 NPs; Gelatin; Nanocomposite; Wettability.