Concurrent Pressure-Induced Superconductivity and Photoconductivity Transitions in PbSe0.5Te0.5

Abstract

Concurrent superconductivity and negative photoconductivity (NPC) are rarely observed. Here, the discovery in PbSe_0.5Te_0.5 of superconductivity and photoconductivity transitions between positive photoconductivity (PPC) and NPC during compression is reported to ≈40 GPa and subsequent decompression, which are also accompanied by reversible structure transitions (3D Fm $\overline{3}$ m ⇌ 2D Pnma ⇌ 3D Pm $\overline{3}$ m). Superconductivity with a maximum T_c of ≈6.7 K coincides with NPC and structure transition of Pnma to Pm $\overline{3}$ m at ≈18 GPa and the latter phase is preserved down to ≈5 GPa with enhanced T_c of ≈6.9 K during decompression. The observations imply the simultaneous superconducting and photoconductive transitions are closely related to the metallic Pm $\overline{3}$ m phase. First-principles calculations suggest the enhanced p-p hybridization and charge transfer between Pb-5p and ligand-p orbitals near the Fermi surface play key roles in electron-phonon interaction of mediating the Cooper pairs in PbSe_0.5Te_0.5. Hall coefficient measurements reveal that photothermal effect enhances electron-phonon interplay, which decreases carrier concentration and mobility and results in the reversal of PPC-NPC. Structure-dependent superconductivity and NPC are jointly mediated by electron-phonon interplay, which is tunable through illumination or cooling at high-pressure. The findings shed light on the origin of superconductive and photoconductive transitions in versatile materials of lead chalcogenides.

Keywords: high pressure; negative photoconductivity; phase transitions; superconductivity.