Transduction of jellyfish superoxide dismutase mediated by TAT peptide ameliorates H2O2-induced oxidative stress in HaCaT cells

Sci Rep. 2024 Dec 28;14(1):31037. doi: 10.1038/s41598-024-82261-6.

Abstract

Superoxide dismutase (SOD) plays important roles in the balance of oxidation and antioxidation in body mostly by scavenging superoxide anion free radicals (O2.-). Previously, we reported a novel Cu/Zn SOD from jellyfish Cyanea capillata, named CcSOD1, which exhibited excellent SOD activity and high stability. TAT peptide is a common type of cell penetrating peptides (CPPs) that efficiently deliver extracellular biomacromolecules into cytoplasm. In this study, we constructed a recombinant expression vector that combined the coding sequences of TAT peptide and CcSOD1, and then obtained sufficient and high-purity TAT-CcSOD1 fusion protein. Compared with some reported SODs/CPP-SODs, TAT-CcSOD1 possessed stronger tolerance to heat and acid-base environment. TAT-CcSOD1 efficiently penetrated cell membrane and significantly enhanced the O2.- scavenging ability in cells, and attenuated H2O2-induced cytotoxicity and NO generation in HaCaT cells. This study serves as a critical step forward for the application of TAT-CcSOD1 as a potential protective/therapeutic agent against oxidative stress-related conditions in the future.

Keywords: Antioxidant; Oxidative stress; Superoxide dismutase; TAT peptide; Transmembrane.

MeSH terms

  • Animals
  • Cell-Penetrating Peptides / chemistry
  • Cell-Penetrating Peptides / metabolism
  • Cell-Penetrating Peptides / pharmacology
  • Gene Products, tat / genetics
  • Gene Products, tat / metabolism
  • HaCaT Cells
  • Humans
  • Hydrogen Peroxide*
  • Oxidative Stress* / drug effects
  • Recombinant Fusion Proteins / genetics
  • Recombinant Fusion Proteins / metabolism
  • Recombinant Fusion Proteins / pharmacology
  • Scyphozoa
  • Superoxide Dismutase* / genetics
  • Superoxide Dismutase* / metabolism
  • Superoxide Dismutase* / pharmacology

Substances

  • Hydrogen Peroxide
  • Superoxide Dismutase
  • Gene Products, tat
  • Recombinant Fusion Proteins
  • Cell-Penetrating Peptides