Phenylarsonic acid (PAA) compounds, widely used in animal husbandry, pose a considerable environmental threat owing to their potential transformation into toxic inorganic arsenic species. To efficiently decontaminate PAA and adsorb secondary As(V), a hybrid CuFe2O4-modified carbon nanotube (CuFe2O4-CNT) filter was developed in this study. The hybrid CuFe2O4-CNT filter functioned as an effective catalyst, convective filtration medium, electrode, and adsorbent. Moreover, it removed 97 % PAA within 80 min in circulation mode under optimal conditions (25 °C, pH0 = 7, peroxymonosulfate [PMS] = 1.5 mM, and voltage = 1.0 V), with a total As removal efficiency of 94 %. Experimental and theoretical studies showed that the (100) and (211) planes of CuFe2O4-CNT contributed to PMS activation and As(V) adsorption, respectively. Quantum chemical calculations and high-performance liquid chromatography-mass spectrometry analysis determined the energy barriers for reactions between the transient state and SO4•- and HO•, based on which potential PAA degradation pathways were proposed. Additionally, the negligible loss of efficiency in practical water samples and acceptable leached metal ion concentrations (Cu < 0.1 mg/L and Fe < 0.15 mg/L) confirmed the reusability and stability of the filter. This study provides a promising strategy for organoarsenic decontamination by combining electrocatalytic PMS oxidation and filtration techniques.
Keywords: CuFe(2)O(4); Electrochemical filtration; Peroxymonosulfate; Phenylarsonic acid.
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