N₂O is a typical by-product in the NH3-SCR process, which requires urgent resolution due to its negative economic and environmental impacts. This study investigates in detail the mechanism of N2O generation on the surface of the Mn-Ce/TiO2 catalyst (Mn-Ce/TiO2-ZS) with anatase {001} facets preferentially exposed. The deep oxidation of NH3 and *NH2 capture of NO via O2 were proved to be the dominant N2O generation pathways. The production of N2O was remarkably reduced by the introduction of a low percentage of water vapor (H2O). The results revealed that low percentage of H2O was capable of enhancing the acid sites on the catalyst surface and facilitating the generation of active hydroxyl species. These active species inhibited the deep dehydrogenation of ammonia and the disintegration of nitrate species on the catalyst surface, as well as suppressing the generation of N2O.
Keywords: Anatase TiO(2) {001} facets; Formation mechanism; N(2)O inhibition; Selective catalytic reduction (SCR).
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