Bio-based waterborne polyurethanes from castor oil, sorbitan monooleate and sodium lignosulfonate with ultraviolet resistance, photothermal effect, corrosion protection and degradation properties

Jinbang Han; Xiuzhong Zhu; Li Tian; Naishuo Yan; Haitao Zhang; Lei Wang

doi:10.1016/j.ijbiomac.2024.138471

Bio-based waterborne polyurethanes from castor oil, sorbitan monooleate and sodium lignosulfonate with ultraviolet resistance, photothermal effect, corrosion protection and degradation properties

Int J Biol Macromol. 2024 Dec 5:287:138471. doi: 10.1016/j.ijbiomac.2024.138471. Online ahead of print.

Authors

Jinbang Han¹, Xiuzhong Zhu², Li Tian¹, Naishuo Yan¹, Haitao Zhang¹, Lei Wang³

Affiliations

¹ Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, State Key Laboratory of Biobased Material and Green Papermaking, Faculty of Light Industry, Key Laboratory for Green Leather Manufacture Technology of China National Light Industry Council, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China.
² Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, State Key Laboratory of Biobased Material and Green Papermaking, Faculty of Light Industry, Key Laboratory for Green Leather Manufacture Technology of China National Light Industry Council, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China; Shandong Huatai Paper Co., Ltd., Shandong Yellow Triangle Biotechnology Industry Research Institute Co. LTD, China. Electronic address: zhuxiuzhong@qlu.edu.cn.
³ School of Petrochemical Engineering, Lanzhou University of Technology, China.

PMID: 39645103
DOI: 10.1016/j.ijbiomac.2024.138471

Abstract

The advancement of bio-based materials derived from renewable resources provides a pivotal strategic approach to address the problems of environmental pollution and scarce fossil resources. In this study, a series of bio-based waterborne polyurethanes (WPUs) with enhanced UV resistance, photothermal effect and corrosion resistance were prepared by using sorbitan monooleate (SP) and castor oil (CO) as vegetable polyols together with the introduction of sodium lignosulfonate modified of diethanolamine (DML). The WPU coatings of only 100 μm thickness, exhibited UV blocking rate > 99 % between 200 and 320 nm. Furthermore, the synthesized WPUs had superior adhesion to aluminum, tinplate, and PVC surface, with adhesion to tinplate of up to 5B and hardness of up to 3H. Additionally, the WPU coatings showed favorable photothermal effect when exposed to 1.05 W/cm² of near-infrared light irradiation, with maximum surface temperature of 93 °C. The WPU coatings demonstrated noteworthy corrosion protection, with high corrosion protection efficiency of 96.97 % on tinplate. This study presents a new strategy for the synthesis of bio-based WPUs with excellent ultraviolet resistance, favorable photothermal effect, corrosion protection, and degradability. The unique properties lay the foundation for the applications of bio-based WPUs in the field of industrial coatings.

Keywords: Bio-based waterborne polyurethanes; Castor oil; Sodium lignosulfonate; Sorbitan monooleate.