Pyrolytic Carbon: An Inexpensive, Robust, and Versatile Electrode for Synthetic Organic Electrochemistry

Angew Chem Int Ed Engl. 2025 Jan 21;64(4):e202417122. doi: 10.1002/anie.202417122. Epub 2024 Nov 16.

Abstract

Synthetic organic electrochemistry is recognized as one of the most sustainable forms of redox chemistry that can enable a wide variety of useful transformations. In this study, readily prepared pyrolytic carbon electrodes are explored in several powerful rAP transformations as well as C-C and C-N bond forming reactions. Pyrolytic carbon provides an alternative to classic amorphous carbon-based materials that are either expensive or ill-suited to large-scale flow reactions.

Keywords: Carbon; Electrochemistry; Electrode; Flow chemistry; Redox chemistry.