Synergistic effects of dual reactive compatibilizers for high-performance fully biodegradable polylactic acid/poly (butyleneadipate-co-terephthalate) composites

Xiangyi Wang; Lingxiao Yu; Fei Cong; Ying Qiu; Lixin Song; Ying Jing; Weihan Chi; Wei Zhang; Hongtao Sun; Liwu Zhang; Jialu Gao; Jiangting Huang; Guangxu Gao; Yujuan Gao; Yuanxia Wang; Na Wang

doi:10.1016/j.ijbiomac.2024.136612

Synergistic effects of dual reactive compatibilizers for high-performance fully biodegradable polylactic acid/poly (butyleneadipate-co-terephthalate) composites

Int J Biol Macromol. 2024 Oct 14:136612. doi: 10.1016/j.ijbiomac.2024.136612. Online ahead of print.

Authors

Xiangyi Wang¹, Lingxiao Yu¹, Fei Cong¹, Ying Qiu², Lixin Song³, Ying Jing¹, Weihan Chi¹, Wei Zhang⁴, Hongtao Sun⁴, Liwu Zhang⁵, Jialu Gao⁶, Jiangting Huang⁶, Guangxu Gao¹, Yujuan Gao¹, Yuanxia Wang¹, Na Wang¹

Affiliations

¹ Liaoning Provincial Key Laboratory for Synthesis and Preparation of Special Functional Materials, Shenyang University of Chemical Technology, Shenyang 110142, Liaoning, China; College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China.
² College of Chemistry, Jilin University, Changchun 130012, China.
³ Liaoning Provincial Key Laboratory for Synthesis and Preparation of Special Functional Materials, Shenyang University of Chemical Technology, Shenyang 110142, Liaoning, China; College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China. Electronic address: lxsong@syuct.edu.cn.
⁴ Shenyang Research Institute of Industrial Technology for Advanced Coating Materials, 110300, China.
⁵ Changchun Shunfeng New Materials Co., Ltd, 130051, China.
⁶ College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China.

PMID: 39414204
DOI: 10.1016/j.ijbiomac.2024.136612

Abstract

The PLA-g-(GMA-co-St) graft copolymer (PGS) was prepared using melt-free radical grafting technology, PGS and ESO were simultaneously employed as compatibilizers for the poly (lactic acid)/poly (butylene adipate-co-terephthalate) (PLA/PBAT) blends. The effects of the type and amount of compatibilizers on the properties of the blends were studied. The results reveal that the epoxy groups in PGS and ESO can interact with the terminal groups of PLA and PBAT. The incorporation of either PGS or ESO separately can improve the compatibility between PLA and PBAT to a considerable degree. However, the introduction of both compatibilizers into the PLA/PBAT blends results in a notable shift of the T_g of the two phases, reduces the size of PBAT particles, and makes their dispersion more uniform. This reveals that the dual reactive compatibilizers can achieve a synergistic effect, significantly reducing the interfacial tension between the two phases and facilitating inter-phase dispersion, ultimately forming a more uniform microstructure. Simultaneously, as the amount of ESO added to the blends gradually increases, the vicat softening temperature and complete decomposition temperature of the blends continue to increase, the notched impact strength and elongation at the break of the blend gradually increase and then decrease. When the ESO amount reaches 4 wt%, the performance of each property increases to 88.9 °C, 447.66 °C, 335.16 %, and 23,359.30 J/m², respectively. At this point, the fracture surface of the blend samples is accompanied by a large-scale plastic deformation. In conclusion, this work represents the first attempt to accomplish synergistic effects via dual reactive compatibilizers. Under the best formulation and processing circumstances, the PLA/PBAT blends greatly increase their overall performance while maintaining biodegradability, hence broadening their application prospects in packaging, agriculture, and disposable tableware.

Keywords: Dual reactive compatibilizers; Interfacial tension; PLA/PBAT blend; Synergistic effect.