The electrochemical CO2 reduction (eCO2R) in membrane electrode assemblies (MEAs) has brought e-chemical production one step closer to commercialization because of its advantages of minimized ohmic resistance and stackability. However, the current performance of reported eCO2R in MEAs is still far below the threshold for economic feasibility where low overall cell voltage (<2 V) and extensive stability (>5 years) are required. Furthermore, while the production cost of e-chemicals heavily relies on the carbon capture and product separation processes, these areas have received much less attention compared to CO2 electrolysis, itself. In this perspective, we examine the current status of eCO2R technologies from both academic and industrial points of view. We highlight the gap between current capabilities and commercialization standards and offer future research directions for eCO2R technologies with the hope of achieving industrially viable e-chemical production.
© 2024 The Authors. Published by American Chemical Society.