Heterogeneous dual-atomic-site catalysts (DACs) hold great potential for diverse applications. However, to date, the synthesis of DACs primarily relies on different atoms freely colliding on the support during synthesis, principally leading to low yields. Herein, we report a general metal ion recognition (MIR) strategy for constructing a series of DACs, including but not limited to Fe1Sn1, Fe1Co1, Fe1Ni1, Fe1Cu1, Fe1Mn1, Co1Ni1, Co1Cu1, Co2, and Cu2. This strategy is achieved by coupling target inorganometallic cations and anions as ion pairs, which are sequentially adsorbed onto a nitrogen-doped carbon substrate as the precursor. Taking the oxygen reduction reaction as an example, we demonstrated that the Fe1Sn1-DAC synthesized through this strategy delivers a record peak power density of 1.218 W cm-2 under 2.0 bar H2-O2 conditions and enhanced stability compared to the single-atom-site FeN4. Further study revealed that the superior performance arises from the synergistic effect of Fe1Sn1 dual vicinal sites, which effectively optimizes the adsorption of *OH and alleviates the troublesome Fenton-like reaction.