N-doped WO3 anchored on porous carbon (N-WO3/PNC) was synthesized as an efficient oxygen reduction catalyst. The N doping reduced the overpotential of WO3 during oxygen reduction. N-WO3/PNC displayed a half-wave potential of 0.85 V. An N-WO3/PNC-based zinc-air battery displayed a high power density of 209.7 mW cm-2.