Engineering valence-mismatched Ti4+ into Fe-based metal-organic-frameworks for enhanced photocatalytic CO2 reduction

Rui Li; Xiang Xue; Minqi Wu; Xuan Zuo; Huilin Hu; Guangshan Zhou; Wang Zhang; Jun Pan; Xiangliang Pan

doi:10.1039/d4cc02714k

Engineering valence-mismatched Ti⁴⁺ into Fe-based metal-organic-frameworks for enhanced photocatalytic CO₂ reduction

Chem Commun (Camb). 2024 Aug 1;60(63):8284-8287. doi: 10.1039/d4cc02714k.

Authors

Rui Li¹, Xiang Xue¹, Minqi Wu¹, Xuan Zuo¹, Huilin Hu¹, Guangshan Zhou², Wang Zhang², Jun Pan², Xiangliang Pan¹

Affiliations

¹ College of Environment, Zhejiang University of Technology, Hangzhou 310014, China.
² College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China.

PMID: 39016027
DOI: 10.1039/d4cc02714k

Abstract

A series of low-dose high-valence Ti⁴⁺ doped MIL-53-NH₂(Fe) photocatalysts were synthesized for visible-light-driven CO₂ reduction. The highest CO₂-to-CO conversion rate of Ti⁴⁺ doped MIL-53-NH₂(Fe) was 7.24 mmol g^-1 h^-1 and the highest CO selectivity was 94% in acetonitrile solvent using [Ru(bpy)₃]²⁺ and triethanolamine.