Construction and application of H1R ligand screening materials based on SMA stabilization and his-tag covalent immobilization of membrane proteins

J Chromatogr A. 2024 Aug 16:1729:465057. doi: 10.1016/j.chroma.2024.465057. Epub 2024 Jun 6.

Abstract

The histamine H1 receptor (H1R) plays a pivotal role in allergy initiation and undergoes the necessity of devising a high-throughput screening approach centered on H1R to screen novel ligands effectively. This study suggests a method employing styrene maleic acid (SMA) extraction and His-tag covalent bonding to immobilize H1R membrane proteins, minimizing the interference of nonspecific proteins interference while preserving native protein structure and maximizing target exposure. This approach was utilized to develop a novel material for high-throughput ligand screening and implemented in cell membrane chromatography (CMC). An H1R-His-SMALPs/CMC model was established and its chromatographic performance (selectivity, specificity and lifespan) validated, demonstrating a significant enhancement in lifespan compared to previous CMC models. Subsequently, this model facilitated high-throughput screening of H1R ligands in the compound library and preliminary activity verification of potential H1R antagonists. Identification of a novel H1R antagonist laid the foundation for further development in this area.

Keywords: Cell membrane chromatography; His-tag; Histamine H1 receptor; Membrane protein immobilization; Styrene maleic acid (SMA).

MeSH terms

  • Animals
  • CHO Cells
  • Cricetulus
  • High-Throughput Screening Assays* / methods
  • Histamine H1 Antagonists / chemistry
  • Histidine / chemistry
  • Humans
  • Immobilized Proteins / chemistry
  • Immobilized Proteins / metabolism
  • Ligands
  • Maleates* / chemistry
  • Membrane Proteins / chemistry
  • Membrane Proteins / metabolism
  • Oligopeptides / chemistry
  • Polystyrenes / chemistry
  • Receptors, Histamine H1* / chemistry
  • Receptors, Histamine H1* / metabolism

Substances

  • Ligands
  • Maleates
  • Receptors, Histamine H1
  • Histidine
  • Immobilized Proteins
  • Membrane Proteins
  • Histamine H1 Antagonists
  • Polystyrenes
  • Oligopeptides
  • styrene-maleic acid polymer