Making nodal lines (NLs) deterministic is quite challenging because directly probing them requires bulk momentum resolution. Here, based on the general scattering theory, we show that the Bloch modes of the circuit metamaterials can be selectively excited with a proper source. Consequently, the transport measurement for characterizing the circuit band structure is momentum resolved. Facilitated by this bulk resolution, we systematically demonstrate the degeneracy conversions ruled by the relative homotopy, including the conversions between Weyl points (WPs) and NLs, and between NLs. It is experimentally shown that two WPs with opposite chirality in a two-band model surprisingly convert into an NL rather than annihilating. And the multiband anomaly (due to the delicate property) in the NL-to-NL conversions is also observed, which in fact is captured by the non-Abelian relative homotopy. Additionally, the physical effects owing to the conversions, like the Fermi arc connecting NLs and the parallel transport of eigenstates, are discussed as well. Other types of degeneracy conversions, such as those induced by spin-orbit coupling or symmetry breaking, are directly amenable to the proposed circuit platform.