Using the Photoluminescence Color Change in Cesium Lead Iodide Nanoparticles to Monitor the Kinetics of an External Organohalide Chemical Reaction by Halide Exchange

Tennyson L Doane; Kevin J Cruz; Tsung-Hsing Chiang; Mathew M Maye

doi:10.1021/acsnanoscienceau.3c00026

Using the Photoluminescence Color Change in Cesium Lead Iodide Nanoparticles to Monitor the Kinetics of an External Organohalide Chemical Reaction by Halide Exchange

ACS Nanosci Au. 2023 Sep 7;3(5):418-423. doi: 10.1021/acsnanoscienceau.3c00026. eCollection 2023 Oct 18.

Authors

Tennyson L Doane¹, Kevin J Cruz¹, Tsung-Hsing Chiang¹, Mathew M Maye¹

Affiliation

¹ Department of Chemistry, Syracuse University, Syracuse, New York 13244, United States.

Abstract

In this work, we demonstrate a photoluminescence-based method to monitor the kinetics of an organohalide reaction by way of detecting released bromide ions at cesium lead halide nanoparticles. Small aliquots of the reaction are added to an assay with known concentrations of CsPbI₃, and the resulting Br-to-I halide exchange (HE) results in rapid and sensitive wavelength blueshifts (Δλ) due to CsPbBr_xI_3-x intermediate concentrations, the wavelengths of which are proportional to concentrations. An assay response factor, C, relates Δλ to Br^- concentration as a function of CsPbI₃ concentration. The observed kinetics, as well as calculated rate constants, equilibrium, and activation energy of the solvolysis reaction tested correspond closely to synthetic literature values, validating the assay. Factors that influence the sensitivity and performance of the assay, such as CsPbI₃ size, morphology, and concentration, are discussed.