A 3D tetrathiafulvalene-based metal-organic framework with intramolecular charge transfer for efficient near-infrared photothermal conversion

Yu Zhang; Zi-Wei Xia; Liang-Jun Shen; Hao Tang; Xu-Feng Luo; Xing Li; Xunwen Xiao

doi:10.1039/d3cc03165a

A 3D tetrathiafulvalene-based metal-organic framework with intramolecular charge transfer for efficient near-infrared photothermal conversion

Chem Commun (Camb). 2023 Sep 21;59(76):11429-11432. doi: 10.1039/d3cc03165a.

Authors

Yu Zhang^{1

2}, Zi-Wei Xia¹, Liang-Jun Shen^{1

3}, Hao Tang^{1

3}, Xu-Feng Luo¹, Xing Li², Xunwen Xiao^{1

3}

Affiliations

¹ College of Material Science and Chemical Engineering, Ningbo University of Technology, 201 Fenghua Road, Ningbo, 315211, China. luoxf@nbut.edu.cn.
² School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China. lixing@nbu.edu.cn.
³ Zhejiang Institute of Tianjin University, 201 Fenghua Road, Ningbo 315211, China.

PMID: 37671497
DOI: 10.1039/d3cc03165a

Abstract

The selection of metal centers can endow donor-metal-accepter (D-M-A) type MOFs with progressive framework dimensions. 3D Cd-based MOFs with intramolecular charge transfer caused by D-M-A exhibit a satisfactory photothermal conversion efficiency of 35.7%, with the temperature rapidly rising from 25 °C to 201 °C in 7 s under 808 nm laser irradiation.