A Genotyping Method for Detecting Foreign Buffalo Material in Mozzarella di Bufala Campana Cheese Using Allele-Specific- and Single-Tube Heminested-Polymerase Chain Reaction

Foods. 2023 Jun 16;12(12):2399. doi: 10.3390/foods12122399.

Abstract

Mozzarella di Bufala Campana (MdBC) cheese is a Protected Designation of Origin (PDO) product that is important for the economy and cultural heritage of the Campania region. Food fraud can undermine consumers' trust in this dairy product and harm the livelihood of local producers. The current methods for detecting adulteration in MdBC cheese due to the use of buffalo material from foreign countries could exhibit limitations associated with the required use of expensive equipment, time-consuming procedures, and specialized personnel. To address these limits here, we propose a rapid, reliable, and cost-effective genotyping method that can detect foreign buffalo milk in a counterpart from the PDO area and in MdBC cheese, ensuring the quality and authenticity of the latter dairy product. This method is based on dedicated allele-specific and single-tube heminested polymerase chain reaction procedures. By using allele-specific primers that are designed to detect the nucleotide g.472G>C mutation of the CSN1S1Bbt allele, we distinguished an amplicon of 330 bp in the amplification product of DNA when extracted from milk and cheese, which is specific to the material originating from foreign countries. By spiking foreign milk samples with known amounts of the counterpart from the PDO area, the sensitivity of this assay was determined to be 0.01% v/v foreign to PDO milk. Based on a rough estimate of its simplicity, reliability, and cost, this method could be a valuable tool for identifying adulterated buffalo PDO dairy products.

Keywords: CSN1S1-deleted allele; PCR analysis; PDO cheese; food fraud; water buffalo milk.

Grants and funding

This research was funded by: (i) MUR-PON for the project PON01_00486 “Sequenziamento del genoma bufalino per il miglioramento quali-quantitativo delle produzioni agroalimentari-GENOBU”; (ii) the National Recovery and Resilience Plan, mission 4, component 2, investment 1.3, call n. 341/2022 of Italian Ministry of University and Research funded by the European Union-NextGenerationEU for the project “ON Foods-Research and innovation network on food and nutrition Sustainability, Safety and Security-Working ON Foods”, project PE00000003, concession decree n. 1550/2022, CUP D93C22000890001; (iii) the Agritech National Research Center funded within the European Union NextGenerationEU program (the National Recovery and Resilience Plan, mission 4, component 2, investment 1.4–D.D. 1032 del 17/06/2022, project CN00000022). This manuscript reflects only the authors’ views and opinions, neither the European Union nor European Commission can be considered responsible for them.