The interaction between a co-catalyst and photocatalyst usually induces spontaneous free-electron transfer between them, but the effect and regulation of the transfer direction on the hydrogen-adsorption energy of the active sites have not received attention. Herein, to steer the free-electron transfer in a favorable direction for weakening S-Hads bonds of sulfur-rich MoS2+x , an electron-reversal strategy is proposed for the first time. The core-shell Au@MoS2+x cocatalyst was constructed on TiO2 to optimize the antibonding-orbital occupancy. Research results reveal that the embedded Au can reverse the electron transfer to MoS2+x to generate electron-rich S(2+δ)- active sites, thus increasing the antibonding-orbital occupancy of S-Hads in the Au@MoS2+x cocatalyst. Consequently, the increase in the antibonding-orbital occupancy effectively destabilizes the H 1s-p antibonding orbital and weakens the S-Hads bond, realizing the expedited desorption of Hads to rapidly generate a lot of visible H2 bubbles. This work delves deep into the latent effect of the photocatalyst carrier on cocatalytic activity.
Keywords: Antibonding Orbitals; Co-Catalysts; Electron Reversal; Photocatalysis; Sulfur-Hydrogen Bonds.
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