Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study

A Ziółkowska; N Szynkiewicz; J Ryl; Ł Ponikiewski

doi:10.1039/d3dt00626c

Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study

Dalton Trans. 2023 Apr 11;52(15):4658-4662. doi: 10.1039/d3dt00626c.

Authors

A Ziółkowska¹, N Szynkiewicz¹, J Ryl², Ł Ponikiewski¹

Affiliations

¹ Gdansk University of Technology, Chemical Faculty, Department of Inorganic Chemistry, Gabriela Narutowicza Str. 11/12, 80-233 Gdansk, Poland. lukasz.ponikiewski@pg.edu.pl.
² Gdansk University of Technology, Faculty of Applied Physics and Mathematics Institute of Nanotechnology and Materials Engineering, Gabriela Narutowicza Str. 11/12, 80-233 Gdansk, Poland.

PMID: 36987876
DOI: 10.1039/d3dt00626c

Abstract

The reactivities of two selected phosphanylphosphaalkenes, Ph₂CP-PtBu₂ (1a) and (p-MeO-Ph)₂CP-PtBu₂ (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes were formed (Cu and Ag dimeric and Au monomeric). All obtained products were air and moisture stable and light insensitive.