Chemical structure and biological activity of the (1 → 3)-linked β-D-glucan isolated from marine diatom Conticribra weissflogii

Int J Biol Macromol. 2023 Jan 1:224:584-593. doi: 10.1016/j.ijbiomac.2022.10.147. Epub 2022 Oct 20.

Abstract

Several polysaccharides are considered to be "biological response modifiers" (BRM) - these refer to biomolecules that augment immune responses and can be derived from a variety of sources. Microalgae produce a diverse range of polysaccharides and could be an excellent source of BRM. Here, we describe the chemical structure and biological activity of water-soluble polysaccharide isolated from the marine diatom Conticribra weissflogii. Using chemical and NMR spectroscopic methods, the polysaccharide was identified as a (1 → 3)-linked β-D-glucan with a low proportion of C-6 substitution by single β-glucose units. The biological activity of this low molecular weight β-glucan (11.7 kDa) was investigated with respect to glioblastoma cell lines (U87 MG and U251) and macrophages (RAW 264.7). We observed that this β-D-glucan did not exhibit cytotoxic activity against glioblastoma cells, but did enhance the phagocytic activity of macrophages, suggesting that it possesses immunomodulatory properties.

Keywords: Glioblastoma; Immunological activity; Microalga; Phagocytosis; Polysaccharide.

MeSH terms

  • Diatoms*
  • Glioblastoma*
  • Glucans / chemistry
  • Humans
  • Immunologic Factors
  • Polysaccharides / chemistry
  • beta-Glucans* / chemistry

Substances

  • Glucans
  • Polysaccharides
  • beta-Glucans
  • Immunologic Factors