The shuttling behavior and slow conversion kinetics of the intermediate lithium polysulfides are the severe obstacles for the application of lithium-sulfur (Li-S) batteries over a wide temperature range. Here, an engineered lamellar yolk-shell structure of In2 O3 @void@carbon for the Li-S battery cathode is developed for the first time to construct a powerful barrier that effectively inhibits the shuttling of polysulfides. On the basis of the unique nanochannel-containing morphology, the continuous kinetic transformation of sulfur and polysulfides is confined in a stable framework, which is demonstrated by using X-ray nanotomography. The constructed Li-S battery exhibits a high cycling capability over 1000 cycles at 1.0 C with a capacity decay rate as low as 0.038% per cycle, good rate performance, and temperature tolerance at -10, 25, and 50 °C. A nondestructive in situ monitoring method of the interfacial reaction resistance in different cycling stages is proposed, which provides a new analysis perspective for the development of emerging electrochemical energy-storage systems.
Keywords: binding energy; cycling stability; nano-CT; secondary batteries; shuttle effect.
© 2021 The Authors. Advanced Science published by Wiley-VCH GmbH.