Coupled photocatalytic alkaline media as a destructive technology for per- and polyfluoroalkyl substances in aqueous film-forming foam impacted stormwater

Abstract

The release of aqueous film forming foam (AFFF) from fuel fire events, fire training events, and other activities has resulted in the presence of persistent and recalcitrant per- and polyfluoroalkyl substances (PFAS) in soil and water nationwide. This study describes the degradation and defluorination of PFAS in stormwater collected from an AFFF-impacted site. Silica-based granular media (SGM) containing titanium dioxide was packed into a column reactor and placed between ultraviolet (UV) lamps to excite the photocatalyst within the SGM and generate free radicals to degrade PFAS present in water that was passed through the media. The system was amended with nucleophiles (hydroxyls) to facilitate the destruction of PFAS. Results showed rapid degradation of 17 identified PFAS, including perfluoroalkyl acid (PFAA) precursors, perfluorosulfonic acids (PFSAs), and perfluorocarboxylic acids (PFCAs). Significant defluorination was observed, indicating PFAS destruction as a result of the coupled photocatalytic and nucleophilic attack. Column reactor experiment findings indicate SGM in the presence of UV light passively degraded a mixture of PFAS in a concentrated waste stream at ambient conditions.

Keywords: AFFF-Impacted stormwater; Fluorotelomers; Granular media; PFAS; Photocatalysis.