One-dimensional cobalt oxide nanotubes with rich defect for oxygen evolution reaction

Abstract

For the electrochemcial hydrogen production, the oxygen evolution reaction (OER) is a pivotal half-reaction in water splitting. However, OER suffers sluggish kinetics and high overpotential, leading to the increase of overall energy consumption and decrease of the energy efficiency. In this work, high-quality cobalt oxide porous nanotubes (Co₃O₄-PNTs) are easily obtained by simple self-template approach. One-dimensional (1D) porous structure provides the large specific surface area, enough abundant active atoms and effective mass transfer. In addition, Co₃O₄-PNTs also own self-stability of 1D architecture, benefitting the their durability for electrocatalytic reaction. Thus, Co₃O₄-PNTs with optimal annealing temperature and time reveal the attractive alkaline OER performance (Tafel slope of 56 mV dec^-1and 323 mV overpotential at 10 mA cm^-2), which outperform the Co₃O₄nanoparticles and benchmark commercial RuO₂nanoparticles. Furthermore, Co₃O₄-PNTs also exhibit excellent OER durability for least 10 h at the 10 mA cm^-2. Overall, Co₃O₄-PNTs with low cost can be serve as a highly reactive and economical catalyst for OER.

Keywords: nanotubes; one-dimensional structures; oxygen evolution reaction; rich defect; self-template approach.