Lithium-rich layered oxides are believed to be the most competitive cathode materials for next-generation lithium-ion batteries (LIBs) due to their high specific capacity, but the poor cycle stability and voltage attenuation severely limit their commercial applications. In this paper, a simple method combining surface treatment via pyrolysis of polyvinyl alcohol (PVA) and potassium ions (K+) doping, is designed to improve the above defects of the cobalt-free Lithium-rich material Li1.2Mn0.6Ni0.2O2 (LMR). The insoluble surface byproduct Li2CO3 and amorphous carbon nanolayer derived from the pyrolysis process of PVA alleviate the corrosion of acidic species with a favorable conductivity, while a large radius of K+ can enlarge the space of the lithium (Li) layer to facilitate the diffusion of Li+, suppress voltage polarization, and synchronously restrain the transformation from a layered structure to a spinel-like structure. After modification, the LMR material exhibits a great initial discharge capacity of 266.0 mAh g-1 at 0.1C, a remarkable rate capability of 159.1 mAh g-1 at 5C and an extremely high capacity retention of 98.5% over 200 cycles at 0.5C with a small voltage drop.
Keywords: Carbon nanolayer; Cycle and rate performance; Lattice spacing; Li(1.2)Mn(0.6)Ni(0.2)O(2); Li(2)CO(3).
Copyright © 2021 Elsevier Inc. All rights reserved.