Recent advances and challenges on removal and recycling of phosphate from wastewater using biomass-derived adsorbents

Abstract

As the severe damage of phosphate enrichment in the water ecosystem and the supply shortage of phosphate rock, developing an efficient method for the removal and recycling of phosphate from wastewater is of great significance. To achieve this goal, adsorption technology has been widely investigated, and various adsorbents were developed. Among them, the biomass-derived adsorbents including biomass-derived carbon-based materials, biomass-based anion exchangers and metal-biomass composites have attracted increasing attention over the past years due to the low cost, abundant renewable raw materials and environmental friendliness. However, different adsorbents usually exhibit variable adsorption performances for phosphate, which highly depends on their design strategies, preparation methods and potential adsorption mechanisms. Thus, this review comprehensively summarizes the recent researches on the removal and recycling of phosphate from wastewater using the biomass-derived adsorbents. Especially, the design strategies, preparation methods, adsorption performances and mechanisms of these reported biomass-derived adsorbents are discussed in detail. Moreover, as the significant strategies to recover and recycling phosphate, the elution and direct use of phosphate-loaded adsorbents as fertilizers are also presented. Although the excellent adsorption performance has been obtained, some challenges are still existing, which should be given more attention in the following researches to facilitate the development and industrial application of biomass-derived adsorbents.

Keywords: Adsorption mechanism; Biomass-derived adsorbents; Design strategies; Phosphate adsorption; Phosphate recycling.